description: |-
  ---------------------------------------------------------------------------
    CTI File converted from Solution Object
  ---------------------------------------------------------------------------

generator: cti2yaml
cantera-version: 3.0.0
date: Sat, 27 Jan 2024 15:25:16 +0100
input-files: [CH4_15_256_9_AP.cti]

units: {length: cm, quantity: mol, activation-energy: cal/mol}

phases:
- name: gas
  thermo: ideal-gas
  elements: [N, H, O, C]
  species: [N2, H2, H, O2, O, H2O, OH, CO, CO2, CH4, CH3, CH2O, C2H6, C2H2,
    CH2(L1)]
  species_qss: [HO2, CH3OH, CH3O, CH2OH, HCO, C2H5, C2H4, C2H3, CH2CO]
  kinetics: custom
  reactions: all
  state:
    T: 300.0
    P: 1.01325e+05

species:
- name: N2
  composition: {N: 2}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.53100528, -1.23660988e-04, -5.02999433e-07, 2.43530612e-09, -1.40881235e-12,
      -1046.97628, 2.96747038]
    - [2.95257637, 1.3969004e-03, -4.92631603e-07, 7.86010195e-11, -4.60755204e-15,
      -923.948688, 5.87188762]
  transport:
    model: gas
    geometry: linear
    diameter: 3.621
    well-depth: 97.53
    polarizability: 1.76
    rotational-relaxation: 4.0
- name: H2
  composition: {H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.34433112, 7.98052075e-03, -1.9478151e-05, 2.01572094e-08, -7.37611761e-12,
      -917.935173, 0.683010238]
    - [2.93286575, 8.26608026e-04, -1.46402364e-07, 1.54100414e-11, -6.888048e-16,
      -813.065581, -1.02432865]
  transport:
    model: gas
    geometry: linear
    diameter: 2.9200000000000004
    well-depth: 38.0
    polarizability: 0.7900000000000001
    rotational-relaxation: 280.0
- name: H
  composition: {H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [2.5, 0.0, 0.0, 0.0, 0.0, 2.547366e+04, -0.44668285]
    - [2.5, 0.0, 0.0, 0.0, 0.0, 2.547366e+04, -0.44668285]
  transport:
    model: gas
    geometry: atom
    diameter: 2.05
    well-depth: 145.0
- name: O2
  composition: {O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.78245636, -2.99673416e-03, 9.84730201e-06, -9.68129509e-09, 3.24372837e-12,
      -1063.94356, 3.65767573]
    - [3.66096065, 6.56365811e-04, -1.41149627e-07, 2.05797935e-11, -1.29913436e-15,
      -1215.97718, 3.41536279]
  transport:
    model: gas
    geometry: linear
    diameter: 3.458
    well-depth: 107.4
    polarizability: 1.6
    rotational-relaxation: 3.8
- name: O
  composition: {O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.1682671, -3.27931884e-03, 6.64306396e-06, -6.12806624e-09, 2.11265971e-12,
      2.91222592e+04, 2.05193346]
    - [2.54363697, -2.73162486e-05, -4.1902952e-09, 4.95481845e-12, -4.79553694e-16,
      2.9226012e+04, 4.92229457]
  transport:
    model: gas
    geometry: atom
    diameter: 2.7500000000000004
    well-depth: 80.0
- name: H2O
  composition: {H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.1986352, -2.0364017e-03, 6.5203416e-06, -5.4879269e-09, 1.771968e-12,
      -3.0293726e+04, -0.84900901]
    - [2.6770389, 2.9731816e-03, -7.7376889e-07, 9.4433514e-11, -4.2689991e-15,
      -2.9885894e+04, 6.88255]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 2.6050000000000004
    well-depth: 572.4
    dipole: 1.8440005262719967
    rotational-relaxation: 4.0
- name: OH
  composition: {H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.99198424, -2.40106655e-03, 4.61664033e-06, -3.87916306e-09, 1.36319502e-12,
      3368.89836, -0.103998477]
    - [2.83853033, 1.10741289e-03, -2.94000209e-07, 4.20698729e-11, -2.4228989e-15,
      3697.80808, 5.84494652]
  transport:
    model: gas
    geometry: linear
    diameter: 2.7500000000000004
    well-depth: 80.0
- name: HO2
  composition: {H: 1, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.30179807, -4.74912097e-03, 2.11582905e-05, -2.42763914e-08, 9.29225225e-12,
      264.018485, 3.7166622]
    - [4.17228741, 1.88117627e-03, -3.46277286e-07, 1.94657549e-11, 1.76256905e-16,
      31.0206839, 2.95767672]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.458
    well-depth: 107.4
    rotational-relaxation: 1.0
- name: CO
  composition: {C: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.5795335, -6.1035369e-04, 1.0168143e-06, 9.0700586e-10, -9.0442449e-13,
      -1.4344086e+04, 3.5084093]
    - [3.0484859, 1.3517281e-03, -4.8579405e-07, 7.8853644e-11, -4.6980746e-15,
      -1.4266117e+04, 6.0170977]
  transport:
    model: gas
    geometry: linear
    diameter: 3.65
    well-depth: 98.1
    polarizability: 1.9500000000000002
    rotational-relaxation: 1.8
- name: CO2
  composition: {C: 1, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [2.356813, 8.9841299e-03, -7.1220632e-06, 2.4573008e-09, -1.4288548e-13,
      -4.8371971e+04, 9.9009035]
    - [4.6365111, 2.7414569e-03, -9.9589759e-07, 1.6038666e-10, -9.1619857e-15,
      -4.9024904e+04, -1.9348955]
  transport:
    model: gas
    geometry: linear
    diameter: 3.763
    well-depth: 244.0
    polarizability: 2.6500000000000004
    rotational-relaxation: 2.1
- name: CH4
  composition: {C: 1, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [5.14911468, -0.0136622009, 4.91453921e-05, -4.84246767e-08, 1.66603441e-11,
      -1.02465983e+04, -4.63848842]
    - [1.65326226, 0.0100263099, -3.31661238e-06, 5.36483138e-10, -3.14696758e-14,
      -1.00095936e+04, 9.90506283]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.7460000000000004
    well-depth: 141.4
    polarizability: 2.6
    rotational-relaxation: 13.0
- name: CH3
  composition: {C: 1, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.6571797, 2.1265979e-03, 5.4583883e-06, -6.6181003e-09, 2.4657074e-12,
      1.6422716e+04, 1.6735354]
    - [2.9781206, 5.797852e-03, -1.97558e-06, 3.072979e-10, -1.7917416e-14,
      1.6509513e+04, 4.7224799]
  transport:
    model: gas
    geometry: linear
    diameter: 3.8
    well-depth: 144.0
- name: CH3OH
  composition: {C: 1, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [5.65851051, -0.0162983419, 6.91938156e-05, -7.58372926e-08, 2.8042755e-11,
      -2.56119736e+04, -0.897330508]
    - [3.52726795, 0.0103178783, -3.62892944e-06, 5.77448016e-10, -3.42182632e-14,
      -2.60028834e+04, 5.16758693]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.6260000000000003
    well-depth: 481.8
    rotational-relaxation: 1.0
- name: CH3O
  composition: {C: 1, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.71180502, -2.80463306e-03, 3.76550971e-05, -4.73072089e-08, 1.8658842e-11,
      1307.72484, 6.57240864]
    - [4.75779238, 7.44142474e-03, -2.69705176e-06, 4.38090504e-10, -2.63537098e-14,
      390.139164, -1.96680028]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.6900000000000004
    well-depth: 417.0
    dipole: 1.7000004851748343
    rotational-relaxation: 2.0
- name: CH2OH
  composition: {C: 1, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.47832317, -1.35069687e-03, 2.78483707e-05, -3.64867397e-08, 1.47906775e-11,
      -3524.76728, 3.30911984]
    - [5.09312037, 5.9475855e-03, -2.06496524e-06, 3.23006703e-10, -1.88125052e-14,
      -4058.13228, -1.84690613]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.6900000000000004
    well-depth: 417.0
    dipole: 1.7000004851748343
    rotational-relaxation: 2.0
- name: CH2O
  composition: {C: 1, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.79372312, -9.90833322e-03, 3.7321999e-05, -3.79285237e-08, 1.31772641e-11,
      -1.43791953e+04, 0.602798058]
    - [3.16952665, 6.1932056e-03, -2.25056366e-06, 3.6597566e-10, -2.20149458e-14,
      -1.45486831e+04, 6.04207898]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.59
    well-depth: 498.0
    rotational-relaxation: 2.0
- name: HCO
  composition: {C: 1, H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.2375461, -3.32075257e-03, 1.40030264e-05, -1.34239995e-08, 4.37416208e-12,
      3872.41185, 3.30834869]
    - [3.92001542, 2.52279324e-03, -6.71004164e-07, 1.05615948e-10, -7.43798261e-15,
      3653.42928, 3.58077056]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.59
    well-depth: 498.0
- name: C2H6
  composition: {C: 2, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.29142572, -5.50154901e-03, 5.99438458e-05, -7.08466469e-08, 2.68685836e-11,
      -1.15222056e+04, 2.66678994]
    - [4.04666411, 0.0153538802, -5.47039485e-06, 8.77826544e-10, -5.23167531e-14,
      -1.24473499e+04, -0.968698313]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.35
    well-depth: 247.49999999999997
    rotational-relaxation: 1.5
- name: C2H5
  composition: {C: 2, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [4.24185905, -3.56905235e-03, 4.82667202e-05, -5.85401009e-08, 2.25804514e-11,
      1.29690344e+04, 4.44703782]
    - [4.32195633, 0.0123930542, -4.3968096e-06, 7.03519917e-10, -4.18435239e-14,
      1.21759475e+04, 0.171103809]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.35
    well-depth: 247.49999999999997
    rotational-relaxation: 1.5
- name: C2H4
  composition: {C: 2, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.95920063, -7.57051373e-03, 5.70989993e-05, -6.91588352e-08, 2.6988419e-11,
      5089.77598, 4.09730213]
    - [3.99182724, 0.0104833908, -3.71721342e-06, 5.94628366e-10, -3.53630386e-14,
      4268.65851, -0.269081762]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.496
    well-depth: 238.4
    rotational-relaxation: 1.5
- name: C2H3
  composition: {C: 2, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [3.36377642, 2.65765722e-04, 2.79620704e-05, -3.72986942e-08, 1.51590176e-11,
      3.44749589e+04, 7.91510092]
    - [4.15026763, 7.54021341e-03, -2.62997847e-06, 4.15974048e-10, -2.45407509e-14,
      3.3856638e+04, 1.72812235]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.7210000000000005
    well-depth: 265.3
    rotational-relaxation: 1.0
- name: C2H2
  composition: {C: 2, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [0.808679682, 0.0233615762, -3.55172234e-05, 2.80152958e-08, -8.50075165e-12,
      2.64289808e+04, 13.9396761]
    - [4.65878489, 4.88396667e-03, -1.60828888e-06, 2.46974544e-10, -1.38605959e-14,
      2.57594042e+04, -3.99838194]
  transport:
    model: gas
    geometry: linear
    diameter: 3.7210000000000005
    well-depth: 265.3
    rotational-relaxation: 2.5
- name: CH2CO
  composition: {C: 2, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 4000.0]
    data:
    - [2.13241136, 0.0181319455, -1.74093315e-05, 9.3533604e-09, -2.01724844e-12,
      -7148.0852, 13.3807969]
    - [5.75871449, 6.35124053e-03, -2.25955361e-06, 3.62321512e-10, -2.15855515e-14,
      -8085.33464, -4.96490444]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: CH2(L1)
  composition: {C: 1, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1000.0, 5000.0]
    data:
    - [3.940188986, -4.129580016e-04, 4.973233657e-06, -4.958481366e-09,
      1.78322289e-12, 4.797518771e+04, 1.274377457]
    - [3.141030372, 2.970840462e-03, -9.123376336e-07, 1.332118658e-10,
      -7.538889311e-15, 4.812953324e+04, 5.104216164]
  transport:
    model: gas
    geometry: linear
    diameter: 3.8
    well-depth: 144.0

reactions:
- equation: 'C2H6 + 3.5 O2 => 2.0 CO2 + 3.0 H2O '  # Reaction 1
  rate-constant: {A: 0.0, b: 0.0, Ea: 0.0}
  
reactions_skeletal:
- equation: H2 + O <=> H + OH  # Reaction 2
  rate-constant: {A: 5.08e+04, b: 2.67, Ea: 6292.0}
- equation: H2 + OH <=> H + H2O  # Reaction 3
  rate-constant: {A: 4.38e+13, b: 0.0, Ea: 6990.0}
- equation: H + O2 <=> O + OH  # Reaction 4
  rate-constant: {A: 1.14e+14, b: 0.0, Ea: 1.5286e+04}
- equation: H + OH + M <=> H2O + M  # Reaction 5
  type: three-body
  rate-constant: {A: 3.5e+22, b: -2.0, Ea: 0.0}
  efficiencies: {CH4: 2.0, H2O: 3.65}
- equation: H2O + O <=> 2 OH  # Reaction 6
  rate-constant: {A: 6.7e+07, b: 1.704, Ea: 1.49868e+04}
- equation: H + HO2 <=> 2 OH  # Reaction 7
  rate-constant: {A: 7.079e+13, b: 0.0, Ea: 295.0}
- equation: H + HO2 <=> H2 + O2  # Reaction 8
  rate-constant: {A: 1.1402e+10, b: 1.0827, Ea: 553.78}
- equation: HO2 + O <=> O2 + OH  # Reaction 9
  rate-constant: {A: 3.25e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + OH <=> H2O + O2  # Reaction 10
  rate-constant: {A: 7.0e+12, b: 0.0, Ea: -1092.96}
  duplicate: true
- equation: HO2 + OH <=> H2O + O2  # Reaction 11
  rate-constant: {A: 4.5e+14, b: 0.0, Ea: 1.09296e+04}
  duplicate: true
- equation: H + O2 (+M) <=> HO2 (+M)  # Reaction 12
  type: falloff
  low-P-rate-constant: {A: 1.737e+19, b: -1.23, Ea: 0.0}
  high-P-rate-constant: {A: 4.65e+12, b: 0.44, Ea: 0.0}
  Troe: {A: 0.67, T3: 1.0e-30, T1: 1.0000000000000002e+30, T2: 1.0e+30}
  efficiencies: {CH4: 2.0, CO: 1.9, CO2: 3.8, H2O: 10.0}
- equation: CO + O (+M) <=> CO2 (+M)  # Reaction 13
  type: falloff
  low-P-rate-constant: {A: 1.173e+24, b: -2.79, Ea: 4191.0}
  high-P-rate-constant: {A: 1.362e+10, b: 0.0, Ea: 2384.0}
  efficiencies: {CO: 1.75, CO2: 3.6, H2O: 12.0}
- equation: CO + OH <=> CO2 + H  # Reaction 14
  rate-constant: {A: 7.015e+04, b: 2.053, Ea: -355.7}
  duplicate: true
- equation: CO + OH <=> CO2 + H  # Reaction 15
  rate-constant: {A: 5.757e+12, b: -0.664, Ea: 331.8}
  duplicate: true
- equation: CH3 + H (+M) <=> CH4 (+M)  # Reaction 16
  type: falloff
  low-P-rate-constant: {A: 2.477e+33, b: -4.76, Ea: 2440.0}
  high-P-rate-constant: {A: 1.27e+16, b: -0.63, Ea: 383.0}
  Troe: {A: 0.783, T3: 74.0, T1: 2941.0, T2: 6964.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: CH4 + H <=> CH3 + H2  # Reaction 17
  rate-constant: {A: 6.14e+05, b: 2.5, Ea: 9587.0}
- equation: CH4 + O <=> CH3 + OH  # Reaction 18
  rate-constant: {A: 1.02e+09, b: 1.5, Ea: 8600.0}
- equation: CH4 + OH <=> CH3 + H2O  # Reaction 19
  rate-constant: {A: 5.83e+04, b: 2.6, Ea: 2190.0}
- equation: CH3 + HO2 <=> CH4 + O2  # Reaction 20
  rate-constant: {A: 1.16e+05, b: 2.23, Ea: -3022.0}
- equation: CH2(L1) + CH4 <=> 2 CH3  # Reaction 21
  rate-constant: {A: 1.326516e+07, b: 1.785451, Ea: 8755.485}
- equation: CH2(L1) + O2 => CO + H + OH  # Reaction 22
  rate-constant: {A: 1.746412e+05, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + O2 <=> CO + H2O  # Reaction 23
  rate-constant: {A: 7.484624e+04, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + O <=> CO + H2  # Reaction 24
  rate-constant: {A: 9.35578e+04, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + O <=> H + HCO  # Reaction 25
  rate-constant: {A: 9.35578e+04, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + H2 <=> CH3 + H  # Reaction 26
  rate-constant: {A: 4.366031e+05, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + OH <=> CH2O + H  # Reaction 27
  rate-constant: {A: 1.871156e+05, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + CO2 <=> CH2O + CO  # Reaction 28
  rate-constant: {A: 8.732062e+04, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + H (+M) <=> CH3 (+M)  # Reaction 29
  type: falloff
  low-P-rate-constant: {A: 1.72555e+28, b: -3.354549, Ea: 1715.485}
  high-P-rate-constant: {A: 1.348086e+17, b: -1.014549, Ea: 485.4846}
  Troe: {A: 0.68, T3: 78.0, T1: 1995.0, T2: 5590.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: CH2(L1) + O2 <=> HCO + OH  # Reaction 30
  rate-constant: {A: 5.715883e+13, b: -0.2145491, Ea: 1985.485}
- equation: CH2(L1) + O2 => CO2 + 2 H  # Reaction 31
  rate-constant: {A: 1.423578e+13, b: -0.2145491, Ea: 1985.485}
- equation: CH2(L1) + O => CO + 2 H  # Reaction 32
  rate-constant: {A: 2.696171e+14, b: -0.2145491, Ea: 485.4846}
- equation: CH3 + O2 <=> CH3O + O  # Reaction 33
  rate-constant: {A: 7.546e+12, b: 0.0, Ea: 2.832e+04}
- equation: CH3 + O2 <=> CH2O + OH  # Reaction 34
  rate-constant: {A: 2.641, b: 3.283, Ea: 8105.0}
- equation: CH3 + O <=> CH2O + H  # Reaction 35
  rate-constant: {A: 5.54e+13, b: 0.05, Ea: -136.0}
- equation: CH3 + OH <=> CH2(L1) + H2O  # Reaction 36
  rate-constant: {A: 5.282e+17, b: -1.518, Ea: 1772.0}
- equation: CH3 + OH <=> CH2OH + H  # Reaction 37
  rate-constant: {A: 4.686e+10, b: 0.833, Ea: 3566.0}
- equation: CH3 + OH <=> CH3O + H  # Reaction 38
  rate-constant: {A: 1.23e+09, b: 1.011, Ea: 1.195e+04}
- equation: CH3 + OH <=> CH2(L1) + H2O  # Reaction 39
  rate-constant: {A: 4.293e+04, b: 2.568, Ea: 3997.8}
- equation: CH3 + HO2 <=> CH3O + OH  # Reaction 40
  rate-constant: {A: 1.0e+12, b: 0.269, Ea: -687.5}
- equation: CH3OH (+M) <=> CH3 + OH (+M)  # Reaction 41
  type: falloff
  low-P-rate-constant: {A: 1.5e+43, b: -6.995, Ea: 9.79922e+04}
  high-P-rate-constant: {A: 2.084e+18, b: -0.615, Ea: 9.25406e+04}
  Troe: {A: -0.4748, T3: 3.558e+04, T1: 1116.0, T2: 9023.0}
- equation: CH3OH (+M) <=> CH2(L1) + H2O (+M)  # Reaction 42
  type: falloff
  low-P-rate-constant: {A: 1.43e+47, b: -8.227, Ea: 9.94171e+04}
  high-P-rate-constant: {A: 3.121e+18, b: -1.017, Ea: 9.1712e+04}
  Troe: {A: 2.545, T3: 3290.0, T1: 4.732e+04, T2: 4.711e+04}
- equation: CH3OH + H <=> CH3O + H2  # Reaction 43
  rate-constant: {A: 1.99e+05, b: 2.56, Ea: 1.03e+04}
- equation: CH3OH + H <=> CH2OH + H2  # Reaction 44
  rate-constant: {A: 3.07e+05, b: 2.55, Ea: 5440.0}
- equation: CH3OH + O <=> CH3O + OH  # Reaction 45
  rate-constant: {A: 3.88e+04, b: 2.5, Ea: 3080.0}
- equation: CH3OH + O <=> CH2OH + OH  # Reaction 46
  rate-constant: {A: 3.88e+05, b: 2.5, Ea: 3080.0}
- equation: CH3OH + OH <=> CH3O + H2O  # Reaction 47
  rate-constant: {A: 150.0, b: 3.03, Ea: -763.0}
- equation: CH3OH + OH <=> CH2OH + H2O  # Reaction 48
  rate-constant: {A: 3.08e+04, b: 2.65, Ea: -806.7}
- equation: CH3 + CH3OH <=> CH3O + CH4  # Reaction 49
  rate-constant: {A: 3220.0, b: 2.425, Ea: 8579.5}
- equation: CH2OH + O2 <=> CH2O + HO2  # Reaction 50
  rate-constant: {A: 1.51e+15, b: -1.0, Ea: 0.0}
  duplicate: true
- equation: CH2OH + O2 <=> CH2O + HO2  # Reaction 51
  rate-constant: {A: 2.41e+14, b: 0.0, Ea: 5017.0}
  duplicate: true
- equation: CH2OH + H <=> CH2O + H2  # Reaction 52
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 0.0}
- equation: CH2OH + OH <=> CH2O + H2O  # Reaction 53
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: CH2OH + O <=> CH2O + OH  # Reaction 54
  rate-constant: {A: 4.2e+13, b: 0.0, Ea: 0.0}
- equation: CH3O + O2 <=> CH2O + HO2  # Reaction 55
  rate-constant: {A: 4.38e-19, b: 9.5, Ea: -5501.0}
- equation: CH3O + H <=> CH2O + H2  # Reaction 56
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + CH3O <=> CH2O + CH4  # Reaction 57
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 0.0}
- equation: H + HCO (+M) <=> CH2O (+M)  # Reaction 58
  type: falloff
  low-P-rate-constant: {A: 1.35e+24, b: -2.57, Ea: 1425.0}
  high-P-rate-constant: {A: 1.09e+12, b: 0.48, Ea: -260.0}
  Troe: {A: 0.7824, T3: 271.0, T1: 2755.0, T2: 6570.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: CO + H2 (+M) <=> CH2O (+M)  # Reaction 59
  type: falloff
  low-P-rate-constant: {A: 5.07e+27, b: -3.42, Ea: 8.4348e+04}
  high-P-rate-constant: {A: 4.3e+07, b: 1.5, Ea: 7.96e+04}
  Troe: {A: 0.932, T3: 197.00000000000003, T1: 1540.0, T2: 1.03e+04}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: CH2O + O <=> HCO + OH  # Reaction 60
  rate-constant: {A: 6.26e+09, b: 1.15, Ea: 2260.0}
- equation: CH2O + H <=> H2 + HCO  # Reaction 61
  rate-constant: {A: 5.74e+07, b: 1.9, Ea: 2740.0}
- equation: CH2O + OH <=> H2O + HCO  # Reaction 62
  rate-constant: {A: 7.82e+07, b: 1.63, Ea: -1055.0}
- equation: CH2O + CH3 <=> CH4 + HCO  # Reaction 63
  rate-constant: {A: 38.3, b: 3.36, Ea: 4312.0}
- equation: HCO + M <=> CO + H + M  # Reaction 64
  type: three-body
  rate-constant: {A: 5.7e+11, b: 0.66, Ea: 1.487e+04}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: HCO + O2 <=> CO + HO2  # Reaction 65
  rate-constant: {A: 7.58e+12, b: 0.0, Ea: 410.0}
- equation: HCO + O <=> CO + OH  # Reaction 66
  rate-constant: {A: 3.02e+13, b: 0.0, Ea: 0.0}
- equation: H + HCO <=> CO + H2  # Reaction 67
  rate-constant: {A: 7.34e+13, b: 0.0, Ea: 0.0}
- equation: HCO + OH <=> CO + H2O  # Reaction 68
  rate-constant: {A: 3.011e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + HCO <=> CH4 + CO  # Reaction 69
  rate-constant: {A: 2.65e+13, b: 0.0, Ea: 0.0}
- equation: HCO + O <=> CO2 + H  # Reaction 70
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2O + H (+M) <=> CH2OH (+M)  # Reaction 71
  type: falloff
  low-P-rate-constant: {A: 1.27e+32, b: -4.82, Ea: 6530.0}
  high-P-rate-constant: {A: 5.4e+11, b: 0.454, Ea: 3600.0}
  Troe: {A: 0.7187, T3: 103.00000000000001, T1: 1291.0, T2: 4160.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: CH3O (+M) <=> CH2O + H (+M)  # Reaction 72
  type: falloff
  low-P-rate-constant: {A: 1.867e+25, b: -3.0, Ea: 2.4307e+04}
  high-P-rate-constant: {A: 6.8e+13, b: 0.0, Ea: 2.617e+04}
  Troe: {A: 0.9, T3: 2500.0, T1: 1300.0, T2: 1.0e+99}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: 2 CH3 (+M) <=> C2H6 (+M)  # Reaction 73
  type: falloff
  low-P-rate-constant: {A: 8.054e+31, b: -3.75, Ea: 981.6}
  high-P-rate-constant: {A: 2.277e+15, b: -0.69, Ea: 174.9}
  Troe: {A: 0.0, T3: 570.0, T1: 1.0000000000000002e+30, T2: 1.0e+30}
  efficiencies: {CO: 2.0, CO2: 3.0, H2O: 5.0}
- equation: C2H5 + H (+M) <=> C2H6 (+M)  # Reaction 74
  type: falloff
  low-P-rate-constant: {A: 1.99e+41, b: -7.08, Ea: 6685.0}
  high-P-rate-constant: {A: 5.21e+17, b: -0.99, Ea: 1580.0}
  Troe: {A: 0.842, T3: 125.0, T1: 2219.0, T2: 6882.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: C2H6 + O <=> C2H5 + OH  # Reaction 75
  rate-constant: {A: 3.55e+06, b: 2.4, Ea: 5830.0}
- equation: C2H6 + H <=> C2H5 + H2  # Reaction 76
  rate-constant: {A: 1.15e+08, b: 1.9, Ea: 7530.0}
- equation: C2H6 + OH <=> C2H5 + H2O  # Reaction 77
  rate-constant: {A: 1.48e+07, b: 1.9, Ea: 950.0}
- equation: C2H6 + CH3 <=> C2H5 + CH4  # Reaction 78
  rate-constant: {A: 5.55e-04, b: 4.72, Ea: 3231.0}
- equation: C2H4 + H (+M) <=> C2H5 (+M)  # Reaction 79
  type: falloff
  low-P-rate-constant: {A: 1.419e+39, b: -6.642, Ea: 5769.0}
  high-P-rate-constant: {A: 9.569e+08, b: 1.463, Ea: 1355.0}
  Troe: {A: -0.569, T3: 299.0, T1: -9147.0, T2: 152.4}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: C2H5 + CH3 <=> C2H4 + CH4  # Reaction 80
  rate-constant: {A: 1.18e+04, b: 2.45, Ea: -2921.0}
- equation: 2 CH3 <=> C2H5 + H  # Reaction 81
  rate-constant: {A: 3.1e+14, b: -0.362, Ea: 1.33725e+04}
- equation: C2H3 + H (+M) <=> C2H4 (+M)  # Reaction 82
  type: falloff
  low-P-rate-constant: {A: 1.4e+30, b: -3.86, Ea: 3320.0}
  high-P-rate-constant: {A: 6.08e+12, b: 0.27, Ea: 280.0}
  Troe: {A: 0.782, T3: 207.49999999999997, T1: 2663.0, T2: 6095.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: C2H4 + M <=> C2H2 + H2 + M  # Reaction 83
  type: three-body
  rate-constant: {A: 2.61e+16, b: 0.0, Ea: 6.7823e+04}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: C2H4 + H <=> C2H3 + H2  # Reaction 84
  rate-constant: {A: 5.07e+07, b: 1.93, Ea: 1.295e+04}
- equation: C2H4 + OH <=> C2H3 + H2O  # Reaction 85
  rate-constant: {A: 2.23e+04, b: 2.745, Ea: 2215.5}
- equation: C2H4 + CH3 <=> C2H3 + CH4  # Reaction 86
  rate-constant: {A: 976.0, b: 2.947, Ea: 1.5148e+04}
  duplicate: true
- equation: C2H4 + CH3 <=> C2H3 + CH4  # Reaction 87
  rate-constant: {A: 8.13e-05, b: 4.417, Ea: 8835.8}
  duplicate: true
- equation: C2H4 + O <=> CH3 + HCO  # Reaction 88
  rate-constant: {A: 7.453e+06, b: 1.88, Ea: 183.0}
- equation: CH2(L1) + CH3 <=> C2H4 + H  # Reaction 89
  rate-constant: {A: 1.247437e+05, b: 1.988656, Ea: -4213.849}
- equation: C2H2 + H (+M) <=> C2H3 (+M)  # Reaction 90
  type: falloff
  low-P-rate-constant: {A: 6.346e+31, b: -4.664, Ea: 3780.0}
  high-P-rate-constant: {A: 1.71e+10, b: 1.266, Ea: 2709.0}
  Troe: {A: 0.788, T3: -1.02e+04, T1: 1.0e-30, T2: 0.0}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: C2H3 + O2 <=> C2H2 + HO2  # Reaction 91
  rate-constant: {A: 2.15e+07, b: 1.19, Ea: 3367.0}
  duplicate: true
- equation: C2H3 + O2 <=> C2H2 + HO2  # Reaction 92
  rate-constant: {A: 46.0, b: 2.76, Ea: -492.8}
  duplicate: true
- equation: C2H3 + O2 <=> CH2CO + OH  # Reaction 93
  rate-constant: {A: 1060.0, b: 2.39, Ea: 6180.0}
  duplicate: true
- equation: C2H3 + O2 <=> CH2CO + OH  # Reaction 94
  rate-constant: {A: 0.526, b: 3.01, Ea: 1777.0}
  duplicate: true
- equation: C2H3 + O2 <=> CH2O + HCO  # Reaction 95
  rate-constant: {A: 2.73e+35, b: -7.32, Ea: 1.182e+04}
  duplicate: true
- equation: C2H3 + O2 <=> CH2O + HCO  # Reaction 96
  rate-constant: {A: 6.08e+15, b: -1.31, Ea: 645.7}
  duplicate: true
- equation: C2H3 + O2 => CH2O + CO + H  # Reaction 97
  rate-constant: {A: 6.36e+35, b: -7.32, Ea: 1.182e+04}
  duplicate: true
- equation: C2H3 + O2 => CH2O + CO + H  # Reaction 98
  rate-constant: {A: 1.42e+16, b: -1.31, Ea: 645.7}
  duplicate: true
- equation: C2H3 + O2 <=> CH3O + CO  # Reaction 99
  rate-constant: {A: 1.03e+11, b: -0.33, Ea: -747.8}
  duplicate: true
- equation: C2H3 + O2 <=> CH3O + CO  # Reaction 100
  rate-constant: {A: 5.77e+21, b: -3.54, Ea: 4772.0}
  duplicate: true
- equation: C2H3 + O2 <=> CH3 + CO2  # Reaction 101
  rate-constant: {A: 7.25e+31, b: -6.7, Ea: 1.044e+04}
  duplicate: true
- equation: C2H3 + O2 <=> CH3 + CO2  # Reaction 102
  rate-constant: {A: 5.32e+13, b: -1.14, Ea: 446.7}
  duplicate: true
- equation: C2H3 + H <=> C2H2 + H2  # Reaction 103
  rate-constant: {A: 9.63525e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> C2H2 + H2O  # Reaction 104
  rate-constant: {A: 3.011e+13, b: 0.0, Ea: 0.0}
- equation: C2H2 + O <=> CH2(L1) + CO  # Reaction 105
  rate-constant: {A: 7.395e+08, b: 1.28, Ea: 2472.0}
- equation: C2H2 + HCO <=> C2H3 + CO  # Reaction 106
  rate-constant: {A: 1.0e+07, b: 2.0, Ea: 6000.0}
- equation: C2H2 + OH <=> CH2CO + H  # Reaction 107
  rate-constant: {A: 7.528e+06, b: 1.55, Ea: 2106.0}
- equation: C2H2 + OH <=> CH3 + CO  # Reaction 108
  rate-constant: {A: 1.277e+09, b: 0.73, Ea: 2579.0}
- equation: CH2CO (+M) <=> CH2(L1) + CO (+M)  # Reaction 109
  type: falloff
  low-P-rate-constant: {A: 3.0e+15, b: 0.0, Ea: 5.7e+04}
  high-P-rate-constant: {A: 3.0e+13, b: 0.0, Ea: 7.1e+04}
  efficiencies: {CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 6.0}
- equation: C2H3 + O <=> CH2CO + H  # Reaction 110
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2CO + H <=> CH3 + CO  # Reaction 111
  rate-constant: {A: 7.77e+08, b: 1.45, Ea: 2780.0}
- equation: CH2CO + OH <=> CH2OH + CO  # Reaction 112
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: -1010.0}
- equation: C2H4 + CH2(L1) <=> C2H3 + CH3  # Reaction 113
  rate-constant: {A: 4.16e+24, b: -3.19, Ea: 9760.0}
  duplicate: true
- equation: C2H4 + CH2(L1) <=> C2H3 + CH3  # Reaction 114
  rate-constant: {A: 4.92e+09, b: 1.02, Ea: 599.77}
  duplicate: true
- equation: C2H2 + O => CH2CO  # Reaction 115
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 1.5e+04}
- equation: CH2CO + O => 2 HCO  # Reaction 116
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 2300.0}
- equation: CH2CO + OH => CH3 + CO2  # Reaction 117
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 0.0}
- equation: O + OH + M <=> HO2 + M  # Reaction 118
  type: three-body
  rate-constant: {A: 1.0e+16, b: 0.0, Ea: 0.0}
- equation: C2H5 + O2 => CH2O + CH3O  # Reaction 119
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 2.4e+04}
- equation: CH2(L1) + HCO <=> CH3 + CO  # Reaction 120
  rate-constant: {A: 1.078469e+14, b: -0.2145491, Ea: 485.4846}
- equation: CH2(L1) + O <=> CO + H2  # Reaction 121
  rate-constant: {A: 2.696171e+14, b: -0.2145491, Ea: 485.4846}
- equation: CH2(L1) + OH <=> CH2O + H  # Reaction 122
  rate-constant: {A: 1.617703e+14, b: -0.2145491, Ea: 485.4846}
- equation: CH2(L1) + CO2 <=> CH2O + CO  # Reaction 123
  rate-constant: {A: 5.931577e+11, b: -0.2145491, Ea: 1485.485}
- equation: CH2(L1) + O <=> CO + 2 H  # Reaction 124
  rate-constant: {A: 1.871156e+05, b: 1.988656, Ea: -4213.849}
- equation: CH2(L1) + CH4 <=> 2 CH3  # Reaction 125
  rate-constant: {A: 2.68199e+05, b: 1.988656, Ea: -4213.849}
- equation: 2 CH3 => C2H4 + H2  # Reaction 126
  rate-constant: {A: 5.0e+14, b: 0.0, Ea: 3.2e+04}
- equation: 2 CH2(L1) => C2H2 + 2 H  # Reaction 127
  rate-constant: {A: 6.470811e+14, b: -0.2145491, Ea: 485.4846}
- equation: C2H6 <=> C2H4 + H2  # Reaction 128
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 7.85e+04}
- equation: CH2O + O => CO2 + 2 H  # Reaction 129
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 5000.0}
- equation: CH2O + OH => CO2 + H + H2  # Reaction 130
  rate-constant: {A: 1.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H2 + HO2 => CH2O + HCO  # Reaction 131
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 1.5e+04}
- equation: CH3O + CO <=> CH3 + CO2  # Reaction 132
  rate-constant: {A: 5.0e+11, b: 0.0, Ea: 6500.0}
- equation: C2H2 + O2 => CH2O + CO  # Reaction 133
  rate-constant: {A: 3.0e+11, b: 0.0, Ea: 2.6e+04}
- equation: C2H4 + O2 => 2 CH2O  # Reaction 134
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 4.8e+04}
- equation: C2H2 + O2 => 2 HCO  # Reaction 135
  rate-constant: {A: 3.0e+11, b: 0.0, Ea: 2.7e+04}
- equation: C2H4 + O2 => CH3O + HCO  # Reaction 136
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 4.3e+04}
- equation: CH3 + O + M => CH3O + M  # Reaction 137
  type: three-body
  rate-constant: {A: 5.0e+16, b: 0.0, Ea: 0.0}
- equation: CH2OH + CH3 => CH2O + CH4  # Reaction 138
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 0.0}
- equation: C2H4 + O <=> C2H3 + OH  # Reaction 139
  rate-constant: {A: 1.083e+07, b: 2.0, Ea: 8781.96}
